By Neal S. Gupta
There are numerous books on homes of chitin and linked biomolecules and their biochemical importance. in spite of the fact that, the current quantity bargains with a large choice of biogeochemical and natural geochemical features of this very important macromolecule written via top authors and specialists within the box. every one bankruptcy is thoroughly peer reviewed and is an up to date account of contemporary study in isotopic, nanostructural, biochemical, microstructural, geochemical, paleontological and experimental elements of chitin formation, distribution and maintenance within the atmosphere and earth heritage.
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Additional info for Chitin: Formation and Diagenesis (Topics in Geobiology)
However, the Palaeozoic problematic taxon Multiplacophora, in spite of having a more complex skeleton, shares several derived characters with chitons. The enigmatic status of the Multiplacophora is due in part to the fact that its members had an exoskeleton of numerous calcium carbonate valves that usually separated after death. An articulated specimen from the Carboniferous period (about 335 million years before present) of Indiana reveals that multi-placophorans had a dorsal protective surface composed of head and tail valves, left and right columns of overlapping valves (five on each side), and a central zone of five smaller valves, all surrounded by an annulus of large spines.
Unlike that of cellulose the HCl hydrolysis of chitin does not encourage crystallite aggregation into spindle-like bundles. Instead, as the hydrolysis proceeds, free amino groups are uncovered and in their protonated state they provide the electrostatic repulsion which stabilizes the suspension. 5 Chitin in Chitons With the aid of chemical methods, the presence of chitin was demonstrated in the Cephalopods shells (Sepia, Loligo, Spirula) (Meyer 1913, 1942; Turek 1933; Lotmar and Picken 1950; Rudall 1955) and also in the radula of Gastropods (Toth and Zechmeister 1939; Rudall 1955).
The lattice parameters were those of a fluorapatite material (Evans and Alvarez 1999). In the core of the major lateral teeth of the chiton Acanthopleura echinata calcium mineralization takes place as an ordered process, with crystalline carbonated apatite being the first mineral deposited. Deposition begins at the top of the tooth 1 Chitin Nanostructures in Living Organisms 23 Fig. 9 TEM of stained sections of the acid-treated radula teeth of the chiton Acanthopleura hirtosa; scale bars 500 nm.
Chitin: Formation and Diagenesis (Topics in Geobiology) by Neal S. Gupta