Download e-book for kindle: Comparative Biochemistry. A Comprehensive Treatise by marcel florkin

By marcel florkin

ISBN-10: 0123955440

ISBN-13: 9780123955449

ISBN-10: 0323141900

ISBN-13: 9780323141901

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FATTY ACID OCCURRENCE AND DISTRIBUTION 19 The extension of the fatty acid molecule by two carbon units is achieved in four consecutive reactions, catalyzed by separate enzymes as follows: (a) One molecule of acetyl coenzyme A condenses with another giving acetoacetyl coenzyme A. (b) Acetoacetyl coenzyme A is reduced to ß-hydroxybutyryl coenzyme A in the presence of reduced diphosphopyridine nucleotide. (c) ß-Hydroxybutyryl coenzyme A undergoes degradation to crotonyl coenzyme A. (d) Crotonyl coenzyme (FAD=*FADH 2 ) -CH2-CH2-CH2-CO-S-CoA CH3-CO-S-C0A Ethylene reductase ( A c y l - C o A - dehydrogenase) CH2-CO-S-CoA -CH 2 -CH =CH-CO-S-CoÄ ±v, - /3-Ketothiolase ™ ro Crotonase - CH 2 -CH - CH2-CO-S-CoA=*-CH=CH-CH2-CO-S-CoA HS-CoA -CH 2 -CO -CH 2 -CO ( D P N * ^ D P N H + H+) /3-Ketoreductase (/3-Hydroxyacyl-CoA-dehydrogenase) FIG.

A. Fats of Nonruminants. 1% palmitic acid [cf. Hilditch ( 3 ) ] . Variations in the amount of dienoic and trienoic acids are probably due to the influence of the dietary fat. For example, the depot fats of grassfed horses contain 17% linolenic and 4% linoleic (183), as compared with 2% linolenic and 22% linoleic acids found in the depot fats of horses fed on oats. These variations accord with the fact that grass fats consist predominantly of linolenic acid, whereas those of oats are rich in linoleic acid (184).

B) Acetoacetyl coenzyme A is reduced to ß-hydroxybutyryl coenzyme A in the presence of reduced diphosphopyridine nucleotide. (c) ß-Hydroxybutyryl coenzyme A undergoes degradation to crotonyl coenzyme A. (d) Crotonyl coenzyme (FAD=*FADH 2 ) -CH2-CH2-CH2-CO-S-CoA CH3-CO-S-C0A Ethylene reductase ( A c y l - C o A - dehydrogenase) CH2-CO-S-CoA -CH 2 -CH =CH-CO-S-CoÄ ±v, - /3-Ketothiolase ™ ro Crotonase - CH 2 -CH - CH2-CO-S-CoA=*-CH=CH-CH2-CO-S-CoA HS-CoA -CH 2 -CO -CH 2 -CO ( D P N * ^ D P N H + H+) /3-Ketoreductase (/3-Hydroxyacyl-CoA-dehydrogenase) FIG.

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Comparative Biochemistry. A Comprehensive Treatise by marcel florkin


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