By International Atomic Energy Agency
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Additional info for Corrosion of research reactor aluminium clad spent fuel in water
A few coupons from the RBOF showed shallow pits due FIG. 7. Possible biofilm passivation on aluminium top external surfaces. 28 BACKGROUND to embedded iron particles. As expected, the galvanic couples showed some crevice corrosion within the stainless steel–aluminium couples and a slight increase in corrosion products on the aluminium–aluminium crevice coupons. 4. Myth of microbially influenced corrosion in the RBOF at SRS In May 1998, a number of articles in the press reported that microbiologically influenced corrosion (MIC) was active on aluminium clad spent fuel stored in the RBOF at SRS.
1. 125 Average Cl– (ppm) NO3 (ppm) SO4 (ppm) pH Average conductivity (µS/m) 1992 Jul. 1992 Jun. 1992 Mar. 1992 Jun. 1992 Dec. 1992 45 75 107 182 365 Mar. 1994 Jul. 1994 Feb. 1995 Aug. 1995 Aug. 1997 Feb. 1999 Jan. 2000 Nov. 1993 Mar. 1994 Jul. 1994 Feb. 1. ) Basin Aug. 1995 Aug. 1997 Feb. 1999 Jan. 2000 Nov. 1993 Mar. 1994 Jul. 1994 Feb. 1995 Sep. 1995 Sep. 1997 Mar. 1999 Aug. 1995 Apr. 1996 Feb. 1 BACKGROUND L L L L P P P P P RBOF RBOF RBOF RBOF RBOF Date Exposure (d) 25 CHAPTER 1 (a) (b) (c) (d) Standard alloy — circular disc; Welded alloy — circular disc; Galvanic couples — circular discs with a 4:1 cathode to anode area ratio; Crevice — pairs.
The new rack contained fewer coupons of the aluminium alloys, with crevice and some galvanic coupons. This rack was designed for withdrawals in years where no scheduled withdrawals were planned in the original programme. Fifteen additional racks were immersed in the RBOF and the L Reactor basin in February 1999, and a new schedule of withdrawals was drawn up. It calls for a minimum of one withdrawal per year over the 20 year programme. Along with colour photography and metallurgical examination of the coupons, a detailed characterization of the basin water during the exposure period will be obtained from the existing water sampling and analysis programme.
Corrosion of research reactor aluminium clad spent fuel in water by International Atomic Energy Agency